STRATUL DUBLU ELECTRIC AL MONTMORILONITULUI. II. ANALIZE COMPARATIVE ALE MODELELOR

Vasile RUSU

Abstract


A fost analizată relaţia potenţial – distanţa de la suprafaţa solidului în volumul soluţiei în modelul Gouy-Chapman, modelul Stern şi modelul modificat Gouy-Chapman. Modelările efectuate conform modelului Stern pentru H-montmo­rilonit şi Al-montmorilonit intercalat cu oligomeri de aluminiu evidenţiază particularităţile stratului dublu electric în proximitatea suprafeţei bazale şi a suprafeţei laterale a montmorilonitului. Dinamica potenţialului în volumul soluţiei prin modelul modificat Gouy-Chapman devine identică modelului Stern, în condiţiile atribuirii caracteristicilor stratului compact din modelul Stern.

EDL FOR MONTMORILLONITE. II. COMPARATIVE ANALYSIS OF MODELS

 

The relationship potential - the distance from the surface of the solid towards the solution by the Gouy-Chapman model, the Stern model, and the modified Gouy-Chapman model were analyzed. Modeling performed according to the Stern model for H-montmorillonite and pillared Al-montmorillonite highlights the peculiarities of the double electric layer close to the basal and edge surfaces. The potential dynamics in the solution by the modified Gouy-Chapman model becomes identical to the Stern model if the main characteristics of Stern layer are attributed.


Keywords


pillared Al-montmorillonite, basal and edge surfaces, electrical double layer.

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